Síntesis, difracción de rayos X, microscopía electrónica de barrido, análisis térmico diferencial y susceptibilidad magnética de la aleación (CuAlSe₂)₁₋ₓ(TaSe)ₓ con x = 0.5 Recibido: /mayo, 2021. Aprobado: /julio, 2021.
Main Article Content
Abstract
Muestras policristalinas de la aleación x = 1/2 del sistema (CuAlSe2)1−x(TaSe)x fueron preparadas por el método de fusión y recocido, caracterizándolas por las técnicas de Difracción de Rayos X (DRX), Microscopia Electrónica de Barrido (MEB), Análisis Térmico Diferencial (ATD) y Susceptibilidad Magnética (SM). Se encontró que las muestras contienen dos fases principales, una pobre y otra rica en Ta, y trazas de TaSe2. La muestra presenta un comportamiento ferromagnético débil con Tc > 300 K, característica que puede ser útil para dispositivos ferromagnéticos a temperatura ambiente.
Descargas
Article Details
References
L.J. Lin, N. Tabatabaie, J.H. Wernick, G.W. Hull, and B. Meagher. Optical, Electronic and Magnetic Properties of the Dilute Magnetic Semiconductor Mn:CuInTe₂. Journal of Electronic Materials, 17:321–324, 1988.
P.M. Shand, P.A. Polstra, I. Miotkowski, and B.C. Crooker. Magnetic Behavior of CuIn₁₋ₓMn₂xTe₂. Journal of Applied Physics, 75:5731–5733, 1994.
N. Tsuji, H. Kitazawa, and G. Kido. Electric and Magnetic Properties of Mn- and Fe- Doped CuInS₂ Compounds. Physics Status Solide, 189:951–954, 2002.
T. Katamani and H. Akai. Magnetic Properties of Chalcopyrite-Based Diluted Magnetic Semiconductors. Journal of Superconductivity, 16(1):95–97, 2003.
T. Katamani and H. Akai. The Magnetic Properties in Transition Metal-Doped Chalcopyrite Semiconductors. Materials Science in Semiconductor Processing, 6:389–301, 2003.
Y.-J. Zhao and A. Zunger. Electronic Structure and Ferromagnetism of Mn-Substituted CuAlS₂, CuGaS₂, CuInS₂, CuGaSe₂ and CuGaTe₂. Physical Review B: Condensed Matter and Materials Physics, 69:104422, 2004.
Y.-J. Zhao and A. Zunger. Site Preference for Mn Substitution in Spintronic Cuᵐⁱⁱⁱx₂ᵛⁱ Chalcopyrite Semiconductors. Physical Review B: Condensed Matter and Materials Physics, 69:075208, 2004.
S. Schorr, M. Tovar, N. Stüβer, and K. Bente. Investigation of Structural Anomaly and Metal Ordering in the Solid Solution 2ZnS-CuInS₂ by Neutron Diffraction. Physica B: Condensed Matter, 350:e411–e414, 2004.^
S. Schorr, R. Höehne, G. Warner, V. Riede, and W. Kockelmann. Investigation of the Solid Solution Series 2(MnX)-CuInX₂ (X = S, Se). Journal of Physics and Chemistry of Solids, 66:1966–1969, 2005.
S. Schorr, R. Höehne, D. Spemann, Th. Doering, and B.V. Korzun. Magnetic Properties Investigations of Mn Substituted ABX₂ Chalcopyrites. Physica Status Solid (a): Applications and Materials Science, 203:2783– 2787, 2006.
S. Schorr, M. Tovar, N. Stuesser, D. Sheptyakov, and G. Geandier. Where the Atoms Are: Cation Disorder and Anion Displacement in Dᴵᴵᴵ Xᵛᴵ– AᴵBᴵᴵᴵXᵛᴵ₂ Semiconductors. Physica B: Condensed Matter, 385–386(Part 1):571– 573, 2006.
A. Pietnoczka, R. Bacewicz, and S. Schorr. Local Structure in (MnS)₂ₓ(CuInS₂)₁₋ₓ Alloy. Physica Status Solidi (a): Applications and Materials Science, 203(11):2746–2750, 2006.
V.M. Novotortsev, G.G. Shabuninab, L.I. Koroleva, T.G. Aminov, R.V. Demin, and S.B. Boichuk. Superparamagnetism in Mn-Doped CuGaTe₂. Inorganic Materials, 43:12–17, 2007.
J. Pérez, P.J. Silva, C.A. Durante-Rincón, J. Primera-Ferrer, and J.R. Fermín. EPR Study of the Diluted Magnetic Semiconductor CuGa₁₋ₓMnₓTe₂. Journal Magnetism and Magnetic Materials, 320:2155–2158, 2008.
P. Grima-Gallardo, E. Calderón, M. Muñoz-Pinto, S. Durán-Piña, M. Quintero, E. Quintero, M. Morocoima, G.E. Delgado, H. Romero, J.M. Briceño, and J. Fernández. Synthesis and Characterization of Cu₃TaIn₃Se₇ and CuTa₂InTe₄. Physica Status Solidi (a): Applications and Materials Science, 205(7):1552– 1559, 2008.
J. Yao, N. Kline, H. Gu, M. Yan, and J.A. Aitken. Effects of Mn Substitution on the Structure and Properties of Chalcopyrite-Type CuInSe₂. Journal Solid State Chemistry, 182:2579–2586, 2009.
J. Yao, C.D. Brunetta, and J.A. Aitken. Suppression of Antiferromagnetic Interactions Through Cu Vacancies in Mn-Substituted CuInSe₂ Chalcopyrites. Journal Physics: Condensed Matter, 24(8):086006, 2012.
P. Grima-Gallardo, O. Izarra, R. Peña, M. Muñoz, S. Durán, M. Quintero, E. Quintero y H. Romero. Comportamiento Magnético de la Aleación (CuInTe₂)₁₋ₓ(TaTe)ₓ con x = 0.25. Revista Cubana de Física, 32(1):18–25, 2015.
J. Yao, B.W. Rudyk, C.D. Brunetta, K.B. Knorr, H.A. Figore, A. Mar, and J.A. Aitken. Mn Incorporation in CuInS₂ Chalcopyrites: Structure, Magnetism, and Optical Properties. Materials Chemistry and Physics, 136(2- 3):415–423, 2012.
S. Torres-Cuenza, P. Grima-Gallardo, M. Muñoz, S. Durán, M. Quintero, L. Nieves y R. Tovar. Magnetic Behavior of the Alloy (CuInSe₂)₁₋ₓ(FeSe)ₓ with x = 0.5. Acta Científica Venezolana, 66(1):56–59, 2015.
P. Grima-Gallardo, S. Torres, M. Quintero, L. Nieves, E. Moreno, and G.E. Delgado. Phase Diagram of (CuInSe₂)₁₋ₓ(FeSe)ₓ Alloys. Journal of Alloys and Compounds, 630:146– 150, 2015.
S. Torres-Cuenza, P. Grima-Gallardo, M. Muñoz, S. Durán, M. Quintero, L. Nieves y R. Tovar. Magnetic Behavior of the Alloy (CuInSe₂)₁₋ₓ(FeSe)ₓ with x = 0.5. Acta Científica Venezolana, 66(1):56–59, 2015.
P. Grima-Gallardo, S. Durán, M. Muñoz, D.P. Rai, and G.E. Delgado. (Cu₀․₄Al₀․₃) TaSe₂: Preparation and Crystal Structure Analysis from X-Ray Powder Diffraction. Southern Brazilian Journal of Chemistry, 28(29):1–6, 2020.
P. Grima-Gallardo, M. Muñoz, S. Durán, G.E. Delgado, E. Pérez-Cappé, and J.A. Aitken. X-Ray Diffraction, Scanning Electron Microscopy and Differential Thermal Analysis of (CuGaSe₂)₁₋ₓ(TaSe)ₓ Alloys System (0 ≤ x ≤ 0.5). Senhri Journal of Multidisciplinary Studies, 5(1):1–18, 2020.
P. Grima-Gallardo, G.E. Delgado, E. Pérez-Cappé, J.A. Aitken y D.P. Rai. Synthesis, Xray Diffraction, and Magnetic Measurements of Cu(Ni,Co)InS₄ Alloys: Superconductor Behavior of CuCo₂InS₄. Revista Latinoamericana de Metalurgia y Materiales, 40(2):131–141, 2020.
P. Grima-Gallardo, M. Palmera, M. Muñoz, S. Durán, M. Quintero, E. Quintero, L. Nieves, E. Moreno, M.A. Ramos, and H. Romero. Superconductivity Observation in a (CuInTe₂)₁₋ₓ(NbTe)ₓ Alloy with x = 0.5. Advanced Materials Science and and Technology, 7(2):1–11, 2013.
M.-L. Doublet, S. Remy, and F. Lemoigno. Density Functional Theory Analysis of the Local Chemical Bonds in the Periodic Tantalum Dichalcogenides TaX₂ (X = S, Se, Te). Journal of Chemical Physics, 113(4):5879–5890, 2000.
A.J. Freeman and Y.-J. Zhao. Advanced Tetrahedrally-Bonded Magnetic Semiconductors for Spintronic Applications. Journal of Physics and Chemistry of Solids, 64(9– 10):1453–1459, 2003.
G.A. Medvedkin, T. Ishibashi, T. Nishi. K. Hayata, Y. Hasewaga, and K. Sato. Room Temperature Ferromagnetism in Novel Diluted Magnetic Semiconductor Cd₁₋ₓMnₓGeP₂. Japanese Journal of Applied Physics, 39: L949, 2000.
S. Cho, S. Choi, G.-B Cha, S.C. Hong, Y. Kim, Yu-J Zhao, A.J. Freeman, J.B. Ketterson, B.J. Kim, Y.C. Kim, and B.Ch. Choi. Room-Temperature Ferromagnetism in (Zn₁₋ₓMnₓ)GeP₂ Semiconductors. Physics Review Letters, 88:257203, 2002.
S. Cho, J. Cho, S.C. Hong, and S. Cho. Mn Doped ZnGeAs₂ and ZnSnAs₂ Single Crystals: Growth, Electrical, and Magnetic Properties. Journal of the Korean Physical Society, 42:S739–S741, 2003.
R.V. Demin, L.I. Koroleva, S.F. Marenkin, S. Mikhailov, T. Aminov, R. Szymczak, and M. Baran. Room-Temperature Ferromagnetism in Mn-Doped CdGeAs₂ Chalcopyrite. Journal Magnetism and Magnetic Materials, 290–291(Part 2):1379–1382, 2005.
L.I. Koroleva, V.Yu. Pavlov, D.M. Zashchirinskiǐ, S.F. Marenkin, S.A. Varnavskiǐ, R. Szymczak, V. Dobrovol’skiǐ and L. Killinskiǐ. Magnetic and Electrical Properties of the ZnGeAs₂: Mn Chalcopyrite. Physics of the Solid State, 49:2121–2125, 2007.
L. Kilanski, K. Szalowski, R. Szymczak, M. Górska, E. Dynowska, P. Aleshkevych, A. Podgórni, A. Avdonin, W. Dobrowolski, I. Fedorchenko, and S. Marenkin. Zn₁₋ₓ(Mn,Co)ₓGeAs₂ Ferromagnetic SemiConductor: Magnetic and Transport Properties. Acta Physica Polonica A, 114(5):1151–1157, 2008.
A. Kochura, R. Laiho, A. Lashkul, E. Lähderanta, M. Shakhov, I. Zakharov, S. Marenkin, A. Molchanov, S. Mikhailov, and G. Jurev. Synthesis and Magnetic Properties of Mn-Doped Cd₀.₁Zn₀.₉GeAs₂ Solid Solutions. Journal of Physics: Condensed Matter, 20(23):335220, 2008.
L. I. Koroleva, D. M. Zashchirinskiǐ, T. M. Khapaeva, S. F. Marenkin, I. V. Fedorchenko, R. Szymczak, B. Krzumanska, V. Dobrovol’skiǐ, and L. Kilanskiǐ. Manganese Doped ZnSiAs₂ Chalcopyrite: A New Advanced Material for Spintronics. Physics Solid State, 51:303–308, 2009.
V.M. Novotortsev, A.V. Kochura, and S.F. Marenkin. New Ferromagnetics Based on Manganese-Alloyed Chalcopyrites AᴵᴵBᴵᵛCᵛ₂. Inorganic Materials, 46:1421–1436, 2010.
L.-J. Lin, N. Tabatabaie, J.H. Wernich, G.W. Hull, and B. Meager. Optical, Electronic and Magnetic Properties of the Dilute Magnetic Semiconductor Mn:CuInTe₂. Journal of Electronic Materials, 17:321–324, 1988.
P.M. Shand, P.A. Polstra, I. Miotkowski and B.C. Crooker. Magnetic Behavior of (CuIn)₁₋ₓMan₂ₓTe₂. Journal Applied Physics, 75(10):5731–5733, 1994.
S. Schorr, R. Höehne, D. Spemann, Th. Doering, and B.V. Korzun. Magnetic Properties Investigations of Mn Substituted ABX₂ Chalcopyrites. Physica Status Solidi (a): Applications and Materials Science, 203(11):2737– 2787, 2006.
V.M. Novotortsev, G.G. Shabubina, L.I. Koroleva, T.G. Aminov, R.V. Demin, and S.V. Boichuk. Superparamagnetism in MnCuGaTe₂. Inorganic Materials, 43(1):12–17, 2007.
P. Grima-Gallardo, F. Alvarado, M. Muñoz, S. Durán, M. Quintero, L. Nieves, E. Quintero, R. Tovar, M. Morocoima, and M.A. Ramos. Superparamagnetism in CuFeInTe₃ and CuFeGaTe₃. Physica Status Solidi (a): Applications and Materials Science, 209(6):1141– 1143, 2012.
P. Grima-Gallardo, L. Méndez, G.E. Delgado, H. Cabrera, E. Pérez-Cappé, I. Zumeta-Dubé, A. Rodríguez, J.A. Aitken, and D.P. Rai. (CuInSe₂)₁₋ₓ(TaSe)ₓ Solid Solutions (0 < x ≤ 0.5): X-Ray Diffraction, Scanning Electron Microscopy, Differential Thermal Analysis and Magnetic Susceptibility. International Journal Experimental Spectroscopic Technnology, 3:016, 2018.
P. Grima-Gallardo, O. Izarra, L. Méndez, S. Torres, M. Quintero, H. Cabrera, E. Pérez-Cappé, I. Zumeta-Dubé, A. Rodríguez, J.A. Aitken and D.P. Rai. Preparation and Characterization of (CuInTe₂)₁₋ₓ(TaTe)ₓ Solid Solutions (0 < x < 1). Journal of Alloys and Compounds, 747:178–188, 2018.
G.E. Delgado, S. Durán, J.A. Aitken, M. Muñoz, and P. Grima-Gallardo. The Crystal Structure of the New Layered Alloy (CuGa)₀.₅₂TaSe₂ Studied by SEM, DTA, and XRPD. Orbital: The Electronic Journal of Chemistry, In press, 2021.
A. Boultif and D. Louer. Powder Pattern Indexing with the Dichotomy Method. Journal of Applied Crystallography, 37:724–731, 20
.